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Differences Between Organic and Inorganic Pigments

2023-07-29 16:10:57
Colorants are mainly categorized into three types: organic pigments, dyes, and inorganic pigments. This article focuses on the differences, classifications, properties, and application scenarios of organic and inorganic pigments, providing valuable insights for industries such as plastics, coatings, and inks.

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1. Classification of Organic and Inorganic Pigments

Pigments are primarily divided into inorganic pigments and organic pigments, distinguished by their molecular structures.

1.1 Inorganic Pigments

Composed of inorganic substances (without carbon elements), such as metal oxides, chromates, carbonates, sulfates, and sulfides. They are further classified by color into:
  • Achromatic pigments: Covering white, gray, and black (e.g., carbon black, titanium white, zinc white).
  • Colored pigments: Including red (iron oxide red), yellow (lead chromate, cadmium yellow, iron yellow), green (chromium oxide green, lead chrome green), blue (iron blue, cobalt blue, ultramarine), and brown pigments.

1.2 Organic Pigments

Containing carbon elements (with carbon ring or carbon chain structures), they are derived from natural or synthetic organic compounds. Classified by chemical structure, the key categories and their proportions are:
  • Azo pigments (59%): The largest category, accounting for ~60% of total organic pigment production. It includes insoluble azo pigments, azo dye lakes, and condensed azo pigments, with a wide color range (yellow, orange, red, brown, blue).
  • Phthalocyanine pigments (24%): High-grade pigments emitting blue-green light, mainly including metal-free phthalocyanine, copper phthalocyanine (dominant in industry), and cobalt phthalocyanine. They have excellent heat resistance, light fastness, and are widely used in inks, plastics, and rubber.
  • Triarylmethane pigments (8%): Featuring bright colors and good tinting strength.
  • Special pigments (6%): Such as functional phthalocyanines with catalytic or photoelectric conversion properties.
  • Polycyclic pigments (3%): Including heterocyclic and fused ring ketone pigments (e.g., quinacridones, diketopyrrolopyrroles, perylenes).

2. Key Differences Between Organic and Inorganic Pigments

The two types of pigments differ significantly in composition, properties, stability, and application scenarios, as detailed below:

2.1 Composition

TypeMain Components
Inorganic PigmentsMetal oxides (e.g., iron oxide, titanium dioxide), chromates, carbonates, sulfides (e.g., aluminum powder, carbon black).
Organic PigmentsCarbon-containing compounds (e.g., azo, phthalocyanine, triarylmethane structures), synthetic or natural organic substances.

2.2 Core Properties

A comprehensive performance comparison is shown in the table:
Performance IndicatorInorganic PigmentsOrganic Pigments
Color RangeNarrow (~60% of standard cards),
dull
Wide (>98% of standard cards),
bright; 30%-50% higher saturation
Tinting StrengthLow (1/3-1/10 of organic ones)High
Heat ResistanceExcellent (>400°C for most)General (150-220°C common;
200-300°C high-performance)
Light Fastness (ISO)Good-excellent
(Grade 7-8)
Moderate (Grade 5-6 common;
Grade 7-8 high-end)
Chemical ResistanceVariable (e.g., ultramarine
acid-sensitive)
Good-excellent (acid/alkali/solvent-resistant
except in salts)
ToxicityHigh for some
(Pb, Hg, Cr-containing)
Low/non-toxic
CostLow-mediumMedium-high (high-performance
types cost more)
OpacityHighMostly transparent;
high-end types can be opaque
Migration (Aqueous)LowHigh (3-5x inorganic ones)

2.3 Application Scenarios
TypeTypical Application Fields
Inorganic Pigments- Construction materials (concrete colorants)
- Marine anti-corrosion coatings
- High-temperature ceramic glazes
- Rust-proof primers (e.g., iron oxide red)
Organic Pigments- Ink industry (45% share, especially four-color printing inks)
- Plastic coloring (PVC, PE)
- High-end automotive coatings (metallic flash paints)
- Stationery and rubber products

3. Summary

Inorganic pigments excel in weather resistance, heat resistance, and cost-effectiveness, making them ideal for construction, anti-corrosion, and high-temperature scenarios. However, they have limitations in color range and toxicity (due to heavy metals).

Organic pigments, with their bright colors, wide color gamut, and low toxicity, are preferred for high-end applications like printing inks, automotive coatings, and plastics. While common organic pigments have lower heat/light fastness, high-performance varieties (e.g., phthalocyanines, quinacridones) match or exceed inorganic pigments in durability, expanding their application scope.

As a crucial fine chemical product, the variety, output, and application of organic pigments continue to grow, driving innovation in industries such as plastics, coatings, and inks.

For more information about Shenhong Pigment's iron oxide pigments and cooperation opportunities, please contact us via the following channels:
  • Head Office Address: No. 1 of Lane 185, South Anxie Road, Jiading District, Shanghai, China
  • WeChat: 18217101261